AlipayClient alipayClient = new DefaultAlipayClient("https://openapi.alipay.com/gateway.do","app_id","your private_key","json","GBK","alipay_public_key","RSA2");
AlipayOpenAppMembersQueryRequest request = new AlipayOpenAppMembersQueryRequest();
request.setBizContent("{" +
"\"role\":\"DEVELOPER\"" +
"  }");
AlipayOpenAppMembersQueryResponse response = alipayClient.execute(request);
if(response.isSuccess()){
System.out.println("调用成功");
} else {
System.out.println("调用失败");
}

IAopClient client = new DefaultAopClient("https://openapi.alipay.com/gateway.do", "app_id", "merchant_private_key", "json", "1.0", "RSA2", "alipay_public_key", "GBK", false);
AlipayOpenAppMembersQueryRequest  request= new AlipayOpenAppMembersQueryRequest() ;
request.BizContent="{" +
"\"role\":\"DEVELOPER\"" +
"  }";
AlipayOpenAppMembersQueryResponse response=client.execute(request);
Console.WriteLine(response.Body);

$aop = new AopClient ();
$aop->gatewayUrl = 'https://openapi.alipay.com/gateway.do';
$aop->appId = 'your app_id';
$aop->rsaPrivateKey = '请填写开发者私钥去头去尾去回车，一行字符串';
$aop->alipayrsaPublicKey='请填写支付宝公钥，一行字符串';
$aop->apiVersion = '1.0';
$aop->signType = 'RSA2';
$aop->postCharset='GBK';
$aop->format='json';
$request = new AlipayOpenAppMembersQueryRequest ();
$request->setBizContent("{" .
"\"role\":\"DEVELOPER\"" .
"  }");
$result = $aop->execute ( $request); 

$responseNode = str_replace(".", "_", $request->getApiMethodName()) . "_response";
$resultCode = $result->$responseNode->code;
if(!empty($resultCode)&&$resultCode == 10000){
echo "成功";
} else {
echo "失败";
}

https://openapi.alipay.com/gateway.do?timestamp=2013-01-01 08:08:08&method=alipay.open.app.members.query&app_id=4973&sign_type=RSA2&sign=ERITJKEIJKJHKKKKKKKHJEREEEEEEEEEEE&version=1.0&biz_content=
  {
"role":"DEVELOPER"
  }

//为确保安全通信，需自行验证响应示例中的sign值是否为蚂蚁金服所提供。

{
	"sign":"ERITJKEIJKJHKKKKKKKHJEREEEEEEEEEEE",
	"alipay_open_app_members_query_response":{
		"msg":"Success",
		"code":"10000",
		"app_member_info_list":[
			{
				"gmt_invite":"2017-09-08 12:00:00",
				"logon_id":"test@e*****e.com",
				"role":"DEVELOPER",
				"gmt_join":"2017-08-12",
				"user_id":"20881234123412341234",
				"nick_name":"张三",
				"portrait":"http://imageg.alipay.com/1",
				"status":"VALID"
			}
		]
	}
}

{
	"sign":"ERITJKEIJKJHKKKKKKKHJEREEEEEEEEEEE",
	"alipay_open_app_members_query_response":{
		"msg":"Service Currently Unavailable",
		"code":"20000",
		"sub_msg":"系统繁忙",
		"sub_code":"isp.unknow-error"
	}
}